Debbie (the other woman who volunteered to help with religious ed) and myself met with the DRE last night. It's not so much that we'll be helping teach (which to me implied that there'd be a teacher and then one of us, assisting, to learn the ropes), but teaching right off the bat. Ourselves.
Assuming that we pass the FBI screening we'll be teaching Basic Faith to 5/6th graders, which I'm comfortable with. The DRE is still previewing text books for next year, so I don't have a curriculum yet.